XYplorer Beta Club

That would be great: hovering over a GUI control configuration item, will show the exact name of the relative entry in the XYPlorer.ini file.

Something similar to Help | Command IDs Menu but instead to reveal the config parameter name.

Te refine it further, it would be nice having a list that for each entry in the XYPlorer.ini shows its path in the config dialog tree

Script it^^ Why? How often is this really necessary? A normal user would never need this (they configure the app via the GUI)
And btw, this is a 1:1 relationship. Only GUI / .ini entries need to be resolved if they have a counterpart in the .ini / GUI.